![]() The IUPAC system treats the shorter alkyl group as a substituent located on position “N” with the remainder of the name based upon what it would be without this substituent. To my knowledge there are no equivalent names that treat the amino group as a substituent. Having said this, it could be easy to mistake methylpropylamine for 1-methylpropylamine. In these cases, the traditional method is perhaps a little simpler where the alkyl groups are straight chains, simply name them in alphabetical order using di and tri if there is more than one of the same type. Secondary amines have two carbon atoms attached to nitrogen and tertiary have three carbon atoms attached to nitrogen. As you can see, the traditional names for more complicated branched molecules start to get a bit ridiculous whereas the IUPAC preferred names seem somewhat more rational. The straight chain and branched isomers of six carbon atom containing amines are summarised in the following table. This is a personal opinion, but I think I see why IUPAC prefer their method. But what about their traditional analogues? 1-methyl-n-butylamine and 1-ethyl-n-propylamine, often written without the “-n-“. We know where we stand with pentan-2-amine and pentan-3-amine (or 2-aminopentane and 3-aminopentane if you prefer). The traditional name for butan-2-amine is sec-butylamine or 1-methylpropylamine (which could be easily confused with methylpropylamine, you will see why in the next section). Isobutylamine would be the equivalent to 2-methylpropan-1-amine (CH 3CH(CH 3)CH 2NH 2). So it must stand to reason that the molecule that IUPAC would prefer to call butan-2-amine (CH 3CH(NH 2)CH 2CH 3) must have the old name isobutylamine? I’m afraid not. However, using the traditional naming system for this molecule would conjure up the somewhat archaic isopropylamine. You could instead call it 2-aminopropane which also makes sense if you use halogenoalkanes as a frame of reference. If you can name alcohols confidently then this won’t present a problem. For example, if I was to ask you to draw propan-2-amine then I would expect most A Level Chemistry students to be able to work out that this is a three carbon molecule with an amino group on the middle carbon atom i.e. This is where I think it is better to move away from the traditional naming system. Other primary amines and branched primary amines Straight chain primary amines with the amino group at the end of the chain are summarised in the following table. Incidentally, for amines of this type containing three or more carbon atoms, the traditional system uses an “n-” before the name. The drawback is that it can get a bit confusing when the functional group moves or you have secondary, tertiary or branched amines. So which is best? I guess the obvious answer is that we should stick close to the convention that the exam board favours. The third way is aminomethane, aminoethane, 1-aminopropane which, in terms of nomenclature, treats amines like halogenoalkanes. The IUPAC names for the corresponding molecules would be methanamine, ethanamine, propan-1-amine. This is the old, traditional method for naming them but not the preferred IUPAC system. Examples include methylamine (CH 3NH 2), ethylamine (CH 3CH 2NH 2) and propylamine (CH 3CH 2CH 2NH 2) and so on. This is the system that you will probably see in text books and on exam paper questions. Straight chain primary amines with amino group at the end of the chainĪll the exam boards seem to favour the “alkylamine” system of naming amines. In this blog post I detail the three most common naming systems and discuss their relative merits. This is because there are many naming conventions that can be used. Of all the functional groups investigated in A Level Chemistry, amines are the trickiest to name. ![]()
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![]() ![]() With additional men and equipment from the European Allies, the US launches a new assault on Soviet-occupied Washington, D.C., reinforcing Allied forces at the Pentagon and, with the assistance of German professor Albert Einstein's Weaponized Prism technology, succeed in liberating the capital from the Soviets. In a daring covert operation, Allied spies infiltrate the Soviet Battle Lab and destroy the two Nuclear Missile silos in Soviet-occupied Poland.įree from the fear of Soviet nuclear counterattack, the European Allies join with the Americans in the war against the Soviets. The Allies promptly launch an amphibious offensive from across Lake Michigan into Soviet-occupied Chicago, freeing the city and destroying the Psychic Amplifier in a surprise attack against the Soviets.īut in retaliation, the Soviet General Vladimir, the chief commander of the invading Soviet forces, declares that he no longer has any use for the city of Chicago and detonates a nuclear device, completely destroying the city.Īlarmed by the nuclear attack on Chicago, the European Allied leaders of France, Germany and Great Britain are willing to lend help to the USA, but only if the American Commander and Special Agent Tanya can send in a strike team to disable the Soviet medium-range nuclear missile silos located along the Polish-German border. Unlike the Psychic Beacon of Washington, the Psychic Amplifier has the power “to do to the country what the Psychic Beacon did to Washington”. ![]() Once the US military and its leaders take refuge in Canada, Allied intelligence discovers that the Soviets have deployed another psychic device, known as the Psychic Amplifier, in the city of Chicago. The American government and military are forced to relocate to Canada to escape from the Soviets and their mind-control technology for the time being. Unfortunately for the Allies, Washington, D.C. However, a quick and valiant counter-strike by the Commander destroys the Psychic Beacon and frees the Allied leaders and military officials from the Soviets' mind control, allowing them to be rescued and evacuated from the city. The Psychic Beacon manages to take control of President Dugan, general Ben Carville, and several other key Allied leaders in the city, who promptly surrender the United States to the Soviets. After recapturing the academy and the airbase and halting the Soviets' advance into the midwest, it is discovered that a Soviet psychic device known as the Psychic Beacon, a device that can mind-control the population of entire cities, has been deployed in Washington, D.C. ![]() Tanya and the Commander are then sent to liberate the US Air Force Academy and the airbase in Colorado Springs. The player, with help from Tanya, successfully repels the Soviet invasion of New York City. The Allied storyline begins with a strike team led by the Commander and Special Agent Tanya into the streets of New York City to defend Fort Bradley and repel the Soviet invasion force there. American president Michael Dugan ordered a nuclear strike on the Soviet Union, but silo operator Jerry Boyd was mind-controlled by Yuri to sabotage the silo, leading to the nuclear missiles detonating on closed silo doors. The Soviets invaded the Allied nations without warning, quickly reaching the United States of America. Suddenly, Allied spies cut contacts with their headquarters, and were seen operating with KGB agents. Premier Alexander Romanov was installed by Allied leaders to the position of Soviet premier and was to keep the USSR in peaceful relations with the West. ![]() Both the Allied campaign and the Soviet campaign start after the events of the original Red Alert, in which the USSR was defeated by the Allies after attempting to "bring revolution to world". Plot Main article: Third World War (Red Alert 2) Red Alert 2 received an average rating of 86% according to GameRankings criteria. The Red Alert 2 singleplayer campaign is structured in an alternate-ending mode as opposed to a progressive story mode introduced in Tiberian Sun Firestorm earlier that year. Red Alert 2 contains two playable factions: the Allies and the Soviets, both of which previously appeared in the first Red Alert game. In September 2001, the expansion pack Yuri's Revenge was released. Set in the early 1970s, Red Alert 2 picks up at the conclusion of the Allied campaign of the first game, making the original idea of Red Alert being a prequel to Tiberian Dawn difficult to realize and separating the Red Alert universe as its own series. Although not originally envisioned by Westwood Studios, Red Alert 2 was created following the success of the original Red Alert. Command & Conquer: Red Alert 2 is a 2.5D real-time strategy computer game developed by Westwood Pacific and released in October 2000 as the follow-up to Command & Conquer: Red Alert. ![]() ![]() 1.1 Season 1: The New World and Chaos Emerald Sagas.For Season 3, air dates for the Japanese run reflect the first date of Kids Station's broadcasts. The airdates for TV Tokyo are listed on the left, while the airdates for the 4Kids English dub are on the right. This would mark the first time that the episodes would air in any format on Japanese television.įor the English dub produced by 4Kids (which aired on FOX on the Saturday morning block FoxBox, later renamed 4Kids TV from Augto May 6, 2006), episodes 1-52 were referred to as Seasons 1-2, each 26 episodes long, and episodes 53-78 were referred to as Season 3, but the Saga Set DVD releases split the episodes into 6 Seasons, each containing 13 episodes. However, as part of Kids Station's 2020 line-up of programming, it was announced that as part a tie in promotion for the Sonic the Hedgehog movie, the network would finally begin broadcasting the remaining episodes in 2020. Episodes 53-78 (collectively known as "Series 2") initially after they were completed and produced, were not aired on TV released on DVD in Japan, but eventually became available through various streaming services years later (episodes 53-78 were first broadcast on TV in France and parts of Asia before they aired on UK/US television). It originally ran consecutively on Sundays from Apto Mawith a total of 52 episodes (collectively known as the Japanese "Series 1"). Continued abuse of our services will cause your IP address to be blocked indefinitely.Sonic X is an anime series based on the Sonic the Hedgehog video game series. Please fill out the CAPTCHA below and then click the button to indicate that you agree to these terms. If you wish to be unblocked, you must agree that you will take immediate steps to rectify this issue. If you do not understand what is causing this behavior, please contact us here. If you promise to stop (by clicking the Agree button below), we'll unblock your connection for now, but we will immediately re-block it if we detect additional bad behavior. Overusing our search engine with a very large number of searches in a very short amount of time.Using a badly configured (or badly written) browser add-on for blocking content.Running a "scraper" or "downloader" program that either does not identify itself or uses fake headers to elude detection.Using a script or add-on that scans GameFAQs for box and screen images (such as an emulator front-end), while overloading our search engine.There is no official GameFAQs app, and we do not support nor have any contact with the makers of these unofficial apps. Continued use of these apps may cause your IP to be blocked indefinitely. ![]() This triggers our anti-spambot measures, which are designed to stop automated systems from flooding the site with traffic.
![]() AND everyone that contributed to the GitHub source.You can download the mod for your Cool Desktop PC on GB.Nyan Cat Lost In Space Description Gather as many food and drinks as you can with Nyan Cat. Warning: Nyan Cat Lost in Space is seriously addictive Play this game at your own risk How to play Nyan Cat Lost in Space: Click the left mouse button to jump. Plays: 83.9K Nyan Cat Lost In Space By Mylostgames - Help Nyan Cat gather food and drinks in space. You want to jump and stay as high as you can. ChrisLad : Fixed coding for Nyan Cat, Boyfriend, and Rock assets Nyan Cat is lost in outer space Nyan cat is hungry Help Nyan Cat to get as much food and drink as possible without falling into the abyss.Goobler : Fixed assets for Nyan Cat and Boyfriend Sprites.CinderAShMaker#0666″ Ported mod assets over to Psych Engine, And Made the Demo.Palladium346: Artist for Nyan Cat’s icons.Timer of Popsicles: Artist for Rock Assets and Stage Background.Souptime: Main Concept artist for sprites, logo artist.Nathan S.: Composer for Nyan and Mod Creator. ![]() Game is free, so if you had fun and would like to keep up-to-update on the mod, make sure to support mod creators on their social media by subscribing, following, liking, etc. You control the best space cute rainbow cat in this casual online platform game. ![]() The goal of the game is to drive through space, which is buried in a huge amount of sweets, candies. Nyan Cat Space is a cute arcade online free game. The video ranked at number 5 on the list of most viewed YouTube videos in 2011. Play Nyan Cat Space game online for free at Scorenga. The video merged a Japanese pop song with an animated cartoon cat with a Pop-Tart for a torso flying through space and leaving a rainbow trail behind. Nyan Cat is a YouTube video uploaded in April 2011, which became an internet meme. ![]() ![]() Borrow ebooks from many public libraries for use with ADE. Use it to read EPUB and PDF books, both online and offline. ![]() Adobe Digital Editions (ADE) is free-to-download and use, and completely ad-free. Seamless fulfillment of books across devices: With this new feature, when a consumer fulfills a book on one device, the book will be automatically downloaded to all the other devices that belong to this consumer (activated using the same user ID). One eBook reader for all your Adobe DRM protected books across your Android Devices, iPad, Mac or PC. ADE’s support for EPUB3 standard allows you: consistent rendering of audio and video content dynamic image resizing without loss in clarity support for multi-column layouts, interactive quizzes, and math formulas. Adobe Digital Editions software offers an engaging way to view and manage media rich eBooks and other digital publications. Organize your books into a beautiful custom library.Įxperience gorgeous media rich books filled with interactive features, videos, and more. Extend your reading experience by transferring books from your personal computer to your Android devices. Use it to read EPUB and PDF books, both online and offline. Adobe Digital Editions is also meant to work together with online ebook stores and public libraries, enabling you to manage the books you buy or borrow directly. Adobe Digital Editions (ADE) is free-to-download and use, and completely ad-free. Select the Download Digital Edition 4.5.11 Windows (8.24MB) option on the page and it should download the installer. ![]() One eBook reader for all your Adobe DRM protected books across your Android Devices, iPad, Mac or PC. ![]() ![]() However, these countries invested massive sums to create the necessary infrastructure. Countries such as China, Russia, and Brazil have been eager to use the games to demonstrate their progress on the world stage. In addition, as researchers Robert Baade and Victor Matheson point out, bidding by developing countries more than tripled after 1988. This allowed the IOC to choose the cities with the most ambitious-and expensive-plans. Los Angeles’ success led to a rising number of cities bidding-from two for the 1988 games to twelve for the 2004 games. The projected cost of $124 million was billions below the actual cost, largely due to construction delays and cost overruns for a new stadium, saddling the city’s taxpayers with some $1.5 billion in debt that took nearly three decades to pay off. ![]() The 1976 Summer Olympics in Montreal came to symbolize the fiscal risks of hosting. In 1972, Denver became the first and only chosen host city to reject its Olympics after voters passed a referendum refusing additional public spending for the games. The killing of protesters in the days before the 1968 Mexico City Games and the fatal assault on Israeli athletes at the 1972 Munich Games tarnished the image of the Olympics, and public skepticism of taking on debt to host the games grew. A 2012 University of Oxford study estimated an average cost overrun of 252 percent for each Summer Olympics since 1976, after adjusting for inflation. The games were growing rapidly, with the number of Summer Olympics participants almost doubling and the number of events increasing by a third during the 1960s. The 1970s marked a turning point, writes Andrew Zimbalist, author of Circus Maximus: The Economic Gamble Behind Hosting the Olympics and the World Cup. Instead, the games were publicly funded, with these advanced countries better positioned to bear the costs due to their larger economies and more advanced infrastructure. The events were held in developed countries, either in Europe or the United States, and in the era before television broadcasting, hosts didn’t expect to make a profit. When did the costs of hosting the games become a concern?įor much of the twentieth century, the staging of the Olympic Games was a manageable burden for the host cities. The multibillion-dollar bill Tokyo faces in the aftermath of the games is not unique: other former host cities still struggle with the debts they incurred, leading some candidate cities for future games to withdraw their bids or scale down their plans. ![]() ![]() The 2020 Summer Olympics in Tokyo highlighted the ongoing debate over the costs and benefits of hosting such a mega-event, especially after the ongoing COVID-19 pandemic forced a year’s delay and sparked public opposition over going ahead with the festivities during a major outbreak. The Pittsburgh Bridge Collapse and the Importance of Infrastructure Investment ![]() ![]() Washington Cog Railway (The Cog) was the first mountain-ascending train in the world. There is an hour to enjoy a snack, explore and take in the spectacular panoramic view, spanning the peaks above the clouds. Washington Cog Railway (The Cog) Tours and Tickets An engineering marvel when it was built in the late 1860s, New Hampshire’s Mt. The mountain-top facility houses restrooms, a cafeteria, gift shop and the Mount Washington Observatory’s Museum. Along the way, lively commentary is given from the brakemen about the many points of visual interest, the history of the railway and the various climate zones passengers will travel through on their journey to the top. One can’t help experience a sense of adventure and history as the train begins the spectacular climb up a 3-mile-long track to the 6,288-foot summit of Mount Washington. ![]() The Cog has maintained its historic roots by allowing passengers to take the three-hour round trip riding in a historic coach powered by a vintage coal-fired steam locomotive. Here visitors can learn the story of the “Railway to the Moon” and its great pioneering inventor, Sylvester Marsh. The Cog Railway Museum is open to the public and free for all. Visitors watch train operations from the decks above while enjoying their lunch. The newly renovated Marshfield Base Station buzzes with activity, and is as picturesque as the mountain itself. It is the second steepest rack railway in the world, with an average grade. It was registered as a National Historic Engineering Landmark in 1976. Recorded SeptemThe Mount Washington Cog Railway is the worlds first mountain-climbing cog railway. In operation since 1869, The Cog has a long history of innovation. Just three hours north of Boston, it is close to the main travel routes, but far enough to get away from it all. ![]() Located in the Presidential Mountain Range of New Hampshire, it is just six miles from the historic Mount Washington Resort and Bretton Woods village. “The Cog” as many fondly call it is the first mountain–climbing cog railway in the world. ![]() ![]() YAMAHA’S ENTIRE OBLIGATION HEREUNDER SHALL BE TO PERMIT USE OF THE SOFTWARE UNDER THE TERMS HEREOF. SPECIFICALLY, BUT WITHOUT LIMITING THE FOREGOING, YAMAHA DOES NOT WARRANT THAT THE SOFTWARE WILL MEET YOUR REQUIREMENTS, THAT THE OPERATION OF THE SOFTWARE WILL BE UNINTERRUPTED OR ERROR-FREE, OR THAT DEFECTS IN THE SOFTWARE WILL BE CORRECTED. NOTWITHSTANDING ANY OTHER PROVISION OF THIS AGREEMENT, YAMAHA EXPRESSLY DISCLAIMS ALL WARRANTIES AS TO THE SOFTWARE, EXPRESS, AND IMPLIED, INCLUDING BUT NOT LIMITED TO THE IMPLIED WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE AND NON-INFRINGEMENT OF THIRD PARTY RIGHTS. The SOFTWARE and related documentation are provided "AS IS" and without warranty of any kind. You expressly acknowledge and agree that use of the SOFTWARE is at your sole risk. This permission to re-download shall not limit in any manner the disclaimer of warranty set forth in Section 5 below. 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PLEASE READ THIS SOFTWARE LICENSE AGREEMENT ("AGREEMENT") CAREFULLY BEFORE USING THIS SOFTWARE. ![]() ![]() ![]() As these examples show, fashion and the fine arts have, and always will, go hand-in-hand.In this tutorial you’ll learn to create a vintage-style fashion illustration. But designers have always worked with artists, long before the commercial pressure to create these lucrative, must-have lines. Today, in our fast-paced digital world, the need to create cult status in a saturated market drives increasing demand for the 'new', which frequently sees fashion houses looking beyond their own front doors for inspiration. Produced in limited numbers, these modern collaborations are photogenic, press-worthy, and add a certain cultural cachet to the world of high fashion. Similarly, the London-based shoe brand Jimmy Choo commissioned Rob Pruitt to sprinkle his magic on a range of accessories, resulting in shoes and bags emblazoned with monochrome animal prints and crystals. In 2011, another Brit artist, Tracey Emin, looked to her own back catalogue to inspire a trio of cashmere pieces for the Australian label Banjo and Matilda for a charity fundraiser, while Paul Smith recently worked with the painter John Tierney to incorporate his own rendition of Smith's Instagram-friendly pink Melrose store in LA into his collection on t-shirts, swimming trunks and more. Later, YSL achieved cult status again for his watershed 1976 Ballets Russes collection which, although not directly inspired by an artist, was immersed in artistic references and had a bohemian, painterly feel to it. St Laurent was also close to Andy Warhol in an era when everyone hung out with rock stars at Studio 54, and the pop artist almost certainly influenced his designs. In its most obvious form, this relationship can result in literal translations of one person's artwork: Yves St Laurent's famed 1965 shift dress, replicating Piet Mondrian's renowned primary-colored block print, highlighted the relevance of cubist art in popular culture in the sixties, long after Mondrian's death in 1944. It's impossible to suggest that British designers are shaped only by British art, because the wonder of the creative mind is that it draws ideas from a plethora of sources – a snippet of vintage oriental silk, a faded photograph, a Moroccan mosaic or a rare sketch by an obscure artist – and amalgamates those into a cocktail of fresh shapes and colors that seem relevant to the modern day. Over the years, art and fashion have enjoyed a rich relationship, sometimes bold and brazen, often more understated, yet always stretching way beyond the boundaries of geography to bring global influences to our wardrobes. ![]() You only have to look at the guest list at London events like the Serpentine Summer Party to see the patchwork of artistic talents that come together to form one of the most dynamic creative centers in the world. From architects and sculptors to contemporary concept installation artists, the creative mind comes in many forms, and often has varied influences. The reality is that creative folk are rarely immersed in the bubble of their own discipline, but absorb a wealth of ideas around them.įashion designers are curious about shape and form, fascinated by color, intrigued by social, historical and cultural references, and therefore find themselves drawn to art galleries, to museums, to artists' studios and archives, and to simply hang out with their contemporaries in the art world, or other design disciplines. But in truth, many of the truly great creatives I’ve seen at design houses over the years are as talented in their own way as any fine artist: using cloth and cutting techniques with the same skillful mastery as a painter wielding brush on canvas. In its simplest form, working with artists can be seen to add an intellectual ‘kudos’ to an industry that's sometimes seen as frivolous. ![]() Watching a designer at work, evolving a collection from sketchbook to shop floor, is akin to witnessing a fascinating alchemy where a mix of diverse cultural influences shape the way we dress.Īnd our industry’s links with the art world have long formed part of that process. ![]() In my work in the fashion industry, I’ve always enjoyed being party to the fashion world’s creative processes. ![]() ![]() ![]() ![]() The Baltic Sea Anomaly is a bizarre object discovered in 2011 at the bottom of the northern Baltic Sea. The team suggested their sonar image showed an object with unusual features of seemingly non-natural origin, prompting speculation published in tabloid newspapers that the object was a sunken UFO. ![]() The Baltic Sea anomaly refers to interpretations of an indistinct sonar image taken by Peter Lindberg, Dennis Åberg and their Swedish “Ocean X” diving team while treasure hunting on the floor of the northern Baltic Sea at the center of the Gulf of Bothnia in June 2011. darling it’s better, down where it’s wetter… modern man once again uncovers what the ancients have known for thousands of years…welcome to the Abzu. Number 9 = In the Phoenician alphabet, the letter “teth” (the serpent) is a cross in a circle, which probably came from the Egyptian alphabet. Every corner of this planet has been touched by their wisdom – but few are willing to shatter their preconceived notions of reality to dig deeper into the story… This is the story of the star people – those who descended from the sky to help Earthlings rebuild after the deluge, and possibly after every cataclysm before the great flood. This is a very ancient story – one that predates homo sapien sapien and homo erectus. The universe/multiverse is only understood in mathematical equations and sacred geometry, and if one desires to uncover the footprints of this ancient race of water-bearers, one must know the language to decode them. Remnants of the DNA of Wada the Sea Giant live on… Master the numbers: 3 6 9, and you will be free. Hermes Trismegistus, another incarnation of Thoth, is known as the “thrice great”. There are 33 segments of the spinal column, also known as Jacob’s ladder or the two serpents of kundalini or the caduceus. There are 33 degrees in Scottish Rite Freemasonry. In occult circles, 9 is considered to be the number of completion and is closely connected with the Dead, especially one’s personal ancestors, and with the forces of the cemetery and the Underworld. The number 9 is also linked with Hecate who is the Queen of Witches who is capable to anticipate and foretell future events involuntarily or otherwise to tell intuitively, as well as Luna, the goddess of the moon in Roman mythology. Such beads may number thirty-three in total or three distinct sets of thirty-three for a total of ninety-nine, corresponding to the names of God. Islamic prayer beads are generally arranged in sets of 33, corresponding to the widespread use of this number in dhikr rituals. According to Al-Ghazali the dwellers of Heaven will exist eternally in a state of being age 33. The divine name Elohim appears 33 times in the story of creation in the opening chapters of Genesis. Hydra, that fearsome water serpent or dragon, is said to have 9 heads. Nikola Tesla famously stated that the numbers 3 6 and 9 were the key to the Universe. Chichen Itza, Kukulcan’s temple, has 9 levels that he descends down every equinox. 9 is the number of the feathered serpent who brings language, wisdom, and spiritual awakening – Quetzalcoatl and Kukulcan are just two of his names. 9 is the Hebrew letter Teth, symbolizes the serpent, and Tethys is the half serpent naiad wife of Okeanos, the Greek god of the ocean. 9 are the sons of the Dragon King of Chinese mythos, who every emperor since has tried to claim lineage from. Jesus died at 33 years old in the 9th hour, nailed to a tree, sacrificing himself for the sake of humanity. Odin hung for 9 days on a tree to acquire the knowledge of the runes. 9 and 33 are always prominently featured in stories of the serpent seed. Wada waded 9 ells deep with his son, Weland (Volundr) on his shoulders. The number 9, the eternal number of the Dragon bloodline. ![]() The Ninth Key represents old Saturn falling and the Moon Goddess victoriously rising. What lies beneath… The letter Teth = Arcanum № 9: Is the Hermit, prudent and wise, it is Solitude. ![]() |
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